Alright, this is crazy. So I swapped out mobos on Volk's new machine because the original one was a piece of shit. When I went to set up the RAID, I must've connected the hard drives just right. The damn thing booted off of the RAID array before I made any changes and went into the Vista installation I had set up using the old mobo. That's fucked up right there.
If the RAID controller is smart enough, it will import the orphaned disks and ask you to accept the new configuration. Or maybe yours just did that automatically...hehe.